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tert-Butyl hydroperoxide

CAS: 75-91-2C4H10O213 suppliers15 productsCompleteness: 100%
Hazard Class:
Hazard Class 5.2
GHS Symbols:
GHS02
GHS05
GHS06
GHS07
GHS08
GHS09
Basic Information

CAS Number

75-91-2

Molecular Formula

C4H10O2

Molecular Weight

90.12

EINECS Number

200-915-7

MDL Number

MFCD00002130

BRN Number

1209229

Chemical Name

tert-Butyl hydroperoxide

Last Updated

7/30/2025

Aliases

Butylhydroperoxid
TBHP
T-BUTYL HYDROPEROXIDE
tert-Butanol peroxide
TERT-BUTYL HYDROPEROXIDE
T-HYDRO(R)
1,1-Dimethylethyl hydroperoxide
1,1-dimethylethyl-hydroperoxid
1,1-dimethylethylhydroperoxide
1,1-dimethylethyl-Hydroperoxide
2-Hydroperoxy-2-methylpropane
2-Methyl-prop-2-yl-hydroperoxide
Aztec t-butyl Hydroperoxide-70, Aq
Butyl hydroperoxide
butylhydroperoxide
Physical and Chemical Properties

Appearance

Colorless liquid with a strong, pungent odor

Appearance State

Liquid. Soluble in water, miscible with ethanol, acetone, benzene.

Color

Colorless

Odor

Strong, pungent odor

Form

Liquid

Melting Point

-2.8

Boiling Point

38 at 17 mmHg

Flash Point

46.1

Density

0.937 @ 20 °C

Vapor Density

3.1 (air=1)

Vapor Pressure

62 mmHg @ 45°C

Refractive Index

1.403 (20°C D)

LogP Value

1.23 (predicted)

Merck Index

1553

Solubility

Slightly soluble in water, readily soluble in most organic solvents like alcohols, ethers, and sodium hydroxide solution.

Water Solubility

miscible with water

Solubility Detail

Solubility in water is 12 g/L, readily soluble in most organic solvents like alcohols, ethers.

Storage Conditions

Store at 2-8°C.

InChI Key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

Safety Data

GHS Hazard Symbols

GHS02
GHS05
GHS06
GHS07
GHS08
GHS09

Hazard Class

Hazard Class 5.2

Signal Word

Danger

Hazard Symbols

O

Risk Codes

R7, R10, R20/21/22, R34, R43, R52/53, R65

UN Number

UN 3109

IARC Classification

Not Classified

WGK Germany

3

RTECS Number

EQ4900000

Auto-ignition Temperature

88-93 (self-accel. dec.)

TSCA Listed

Listed (Active)

Packing Group

II

Customs Code

29094990

Occupational Exposure Band (OEB)

Not Specified

Occupational Exposure Limit (OEL)

ACGIH C: 0.1 ppm (皮肤)

Immediately Dangerous to Life or Health (IDLH)

40 ppm

Safety Statements

S3/7, S14, S16, S17, S24, S26, S36/37/39, S45, S61, S62

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